MCSE's are generally tied in with computer experience, i.e. those who have experience of the Windows Server family (plus a couple of the BackOffice systems - e.g. Exchange Server, etc).
For a starter, I'd investigate the A+ Certification (recognised more in the US, I believe?), or (possibly), a MCDTS (Microsoft Desktop Support Technician). No idea if the MCDTS qualification is "recognised" enough as a starter qualification, so the A+ is probably a good start? Check to see if the job market requests them before starting off, however.
Nothing is guaranteed, however... I started with a Computer Studies Degree, and then into a lowly telephone support role. After an MCP (plus experience in that product), I moved into a desktop support role, gradually studying for an MCSE through various desktop/server support roles (the exams were based on systems that I was actually supporting at the time).
An MCSE is only really required if you have the combined experience, although there a lot of "paper" MCSE's out there - i.e. people who have taken the exams, but wouldn't know how to even log onto a server (yup, I've seen plenty of those around).
Best of luck, though. 
